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Coupling Agents: Titanate vs Aluminate vs Zirconate

Non-silane coupling agents offer distinct advantages over silanes for certain polymer/filler systems, particularly at elevated temperatures or with non-siliceous minerals.

SpecZEMSIL CT-101ZEMSIL CT-201ZEMSIL CA-821ZEMSIL CA-831ZEMSIL CZ-201ZEMSIL CZ-301
Metal centerTiTiAlAlZrZr
TypeMonoalkoxy titanateChelate titanateIsopropyl aluminatePhosphate aluminateNeopentyl zirconateNeopentyl pyrophosphate Zr
Max use temp~250 °C~180 °C~200 °C~220 °C~280 °C>300 °C
Best fillerCaCO₃, talc, BaSO₄Mineral, PVCAlumina, kaolinPhosphate mineralsHigh-temp mineralHigh-temp flame-retardant
Best forFilled PP/PE/nylonPVC processing, cablePolyolefin, rubberPhosphate-rich systemsThermal-stable compositesExtreme-temp composites, nuclear

How to choose

  • For filled polyolefin (PP/PE) or nylon compounding: CT-101 monoalkoxy titanate.
  • For PVC and heat-stabilised cable compounds: CT-201 chelate titanate.
  • For standard rubber or polyolefin with alumina/kaolin filler: CA-821.
  • When filler is phosphate-based or system contains flame retardants: CA-831.
  • For >250 °C service or moisture-sensitive high-performance composites: CZ-series zirconate.

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Coupling Agents: Titanate vs Aluminate vs Zirconate | ZEMSIL® | ZEMSIL®